Dewpoint
A calculated temperature at which water vapor will condense.

Double glazing
Two panes of glass enclosing a hermetically-sealed air space.

Distortion
An optical effect obtained on the glazing surface.

Double Glazed Units
Two panes of glass enclosing a hermetically-sealed air space.

Design Heat Loss
The calculated ratio for heat which is transmitted from a warm interior to a cold exterior.

Dry Glazing
A glazing process which does not use chemical compounds, only dry, mechanical fixings.

dB
A unit of sound measurement.

Deflection
The term applied to the physical displacement of glass from its original position under load.

Dual sealed system
A primary seal of polyisobutylene and a secondary seal of polysulphide, polyurethane or silicone ensuring the effective and durable sealing of double-glazed units. ]]> glass-glossary-d.html/feed 0 glass-glossary-c.html glass-glossary-c.html#comments Sat, 24 Apr 2010 09:11:49 +0000 Glass Engineer System @p=145 Continue reading →]]> Condensation
When water vapour from the air comes into contact with cold surfaces, the vapour condenses on the cooler surface of the glass forming a foggy effect.

Convection
A transfer of heat by movement of air.

Came
A narrow flat bar of lead, zinc or copper, which holds together the pieces of glass in copperlight glazing or leaded lights.

Caulk
A term used to describe a void filled with sealant.

Clear Glass
Mostly composed of soda, lime and silica to obtain a very clear type of glass.

Compound
A substance formed from two or more elements chemically united in fixed proportions.

Conduction
The transmission of heat through, along or from glass to another material in contact with it.

Cullet
Recycled glass used in the manufacture of clear float glass.

Cutting
A process in which glass is trimmed, also for decorative purposes.

Celsius
Temperatures expressed with the Celsius scale are based on a division of one hundred degrees between the freezing point and boiling point of water.

Chemical Strengthening
A process in which glass is covered by a chemical solution thus producing a higher mechanical resistance.

Cold End
A term which describes operation performed on glass when it is already formed and cooled, such as cutting, grinding, acid etching, engraving, etc.

CNC
Stands for computer numerical control.

Coating
A thin layer or covering which changes the basic composition of glass.

Cavity
The cavity formed by the spacer bar between the two panes of glass in double-glazed units. It is generally filled with air. ]]> glass-glossary-c.html/feed 0 glass-glossary-b.html glass-glossary-b.html#comments Fri, 23 Apr 2010 09:09:18 +0000 Glass Engineer System @p=143 Continue reading →]]> B.T.U.
British Thermal Unit

Bead or Glazing Bead
A strip of wood, metal or other suitable material attached to the rebate to retain the glass.

Bevelling
The process by which an edge of glass is finished to a bevel angle.

Blibe
A cavity which is larger than seed and filled with gas.

Blister
A cavity in glass filled with gas.

Bond Breaker
A substance to which the sealant will not stick.

Brilliant Cutting
Abrasive and polishing wheels are used on flat glass to obtain a decorative effect.

Butyl
A synthetic rubber mostly used for the production of insulating glass units.

Batch
A quantity of raw materials (soda lime, silica sand, calcium, oxide, soda and magnesium) properly weighted and mixed to be introduced into the glass furnace where they are melted at 1500

Ball Gatherer
A special machine designed to collect a defined quantity of molten glass from the glass furnace.

Bent glass
Bent glass is a normal glass, which is curved with a special process.

Bending
A process used to produce bent glass in which a plate of glass is placed in a horizontal mould and then slowly heated at approximately 600

Blowpipe
An iron or steel pipe for blowing glass.

Bulletproof Glass
Designed and produced to resist penetration by bullets.

Body-tinted glass
Tranparent float glass with a consistent colour throughout its depth.

Bevell
A decorative form of edge working.

Bow
A form of distortion in toughened and heat strengthened glass, inherent to the manufacturing process.

Blast-resistance glass
The ability of glass to stand blast pressure from an explosion. ]]> glass-glossary-b.html/feed 0 glass-glossary-a.html glass-glossary-a.html#comments Thu, 22 Apr 2010 09:09:10 +0000 Glass Engineer System @p=141 Continue reading →]]> A Abrasion
A method of shallow, decoration grinding using a diamond wheel. The decorated areas are then left unpolished.

Absorptance
The ratio of solar radiation versus total radiation absorbed by a glazing system.

Air infiltration
The ratio of air leaking through cracks in building.

Air leakage rating
Air infiltration ratio.

Argon
An inert, nontoxic gas used to fill insulating units, thus improving thermal performance.

Acid Etching
A process, manly used for glass decoration, where the glass surface is treated with hydrofluoric acid. Acid-etched glass has a distinctive, uniformly smooth and satin-like appearance.

Anneal
A process used to cool formed glass at controlled temperature rates to prevent thermal stresses.

Annealed Glass
During the float glass process, the hot glass is gently cooled in the “annealing lehr”, which releases any internal stresses from the glass to enable the cutting and further processing of the glass post manufacture.

Annealing Range
Determines the limits of temperature within which glass may be annealed.

Antique glass
A general term describing a very old piece of glass, perhaps even several centuries old.

Arrised Edge
A basic form of edge working, by removing the sharp edges of cut panes of glass.

Attenuation
Reduction of the intesity of sound as a result of energy conversion from sound to motion or heat.

Acoustic Insulation
The ratio of external sounds passing through a glazing surface.

Alarm Glass
Is a special laminated glass designed and manufactured for security purposes. The interlayer is embedded with a very thin wire and then “sandwiched” between two or more sheets of glass.

Acid Polishing
This process is used to remove obscurities from etched surfaces.

Antique mirror
Is a decorative silvered glass mostly used for interiors.

Anti-reflective glass
Anti-reflective glass is float glass with a specially-designed coating which reflects a very low % of light. It offers maximum transparency and optical clarity, allowing optimum viewing through the glass at all times.

Active coating material
Whose properties are affected by external stimulus.

Aspect ratio
The ratio of the longer side of a pane to its shorter side. ]]> glass-glossary-a.html/feed 0 calculation-of-glass-properties.html calculation-of-glass-properties.html#comments Thu, 22 Apr 2010 03:28:28 +0000 Glass Engineer System @p=127 Continue reading →]]> The calculation of glass properties (glass modeling) is used to predict glass properties of interest or glass behavior under certain conditions (e.g., during production) without experimental investigation, based on past data and experience, with the intention to save time, material, financial, and environmental resources, or to gain scientific insight. It was first practised at the end of the 19th century by A. Winkelmann and O. Schott. The combination of several glass models together with other relevant functions can be used for optimization and six sigma procedures. In the form of statistical analysis glass modeling can aid with accreditation of new data, experimental procedures, and measurement institutions (glass laboratories).

History

Historically, the calculation of glass properties is directly related to the founding of glass science. At the end of the 19th century the physicist Ernst Abbe developed equations that allow calculating the design of optimized optical microscopes in Jena, Germany, stimulated by co-operation with the optical workshop of Carl Zeiss. Before Ernst Abbe’s time the building of microscopes was mainly a work of art and experienced craftsmanship, resulting in very expensive optical microscopes with variable quality. Now Ernst Abbe knew exactly how to construct an excellent microscope, but unfortunately, the required lenses and prisms with specific ratios of refractive index and dispersion did not exist. Ernst Abbe was not able to find answers to his needs from glass artists and engineers; glass making was not based on science at this time.[2]

In 1879 the young glass engineer Otto Schott sent Abbe glass samples with a special composition (lithium silicate glass) that he had prepared himself and that he hoped to show special optical properties. Following measurements by Ernst Abbe, Schott’s glass samples did not have the desired properties, and they were also not as homogeneous as desired. Nevertheless, Ernst Abbe invited Otto Schott to work on the problem further and to evaluate all possible glass components systematically. Finally, Schott succeeded in producing homogeneous glass samples, and he invented borosilicate glass with the optical properties Abbe needed.[2] These inventions gave rise to the well-known companies Zeiss and Schott Glass (see also Timeline of microscope technology). Systematic glass research was born. In 1908, Eugene Sullivan founded glass research also in the United States (Corning, New York).[3]

At the beginning of glass research it was most important to know the relation between the glass composition and its properties. For this purpose Otto Schott introduced the additivity principle in several publications for calculation of glass properties.[4][5][6] This principle implies that the relation between the glass composition and a specific property is linear to all glass component concentrations, assuming an ideal mixture, with Ci and bi representing specific glass component concentrations and related coefficients respectively in the equation below. The additivity principle is a simplification and only valid within narrow composition ranges as seen in the displayed diagrams for the refractive index and the viscosity. Nevertheless, the application of the additivity principle lead the way to many of Schott’s inventions, including optical glasses, glasses with low thermal expansion for cooking and laboratory ware (Duran), and glasses with reduced freezing point depression for mercury thermometers. Subsequently, English[7] and Gehlhoff et al.[8] published similar additive glass property calculation models. Schott’s additivity principle is still widely in use today in glass research and technology.[9][10]

Global models

Schott and many scientists and engineers afterwards applied the additivity principle to experimental data measured in their own laboratory within sufficiently narrow composition ranges (local glass models). This is most convenient because disagreements between laboratories and non-linear glass component interactions do not need to be considered. In the course of several decades of systematic glass research thousands of glass compositions were studied, resulting in millions of published glass properties, collected in glass databases. This huge pool of experimental data was not investigated as a whole, until Bottinga,[13], Kucuk[14], Priven[15], Choudhary[16], Mazurin[17], and Fluegel[18][19] published their global glass models, using various approaches. In contrast to the models by Schott the global models consider many independent data sources, making the model estimates more reliable. In addition, global models can reveal and quantify non-additive influences of certain glass component combinations on the properties, such as the mixed-alkali effect as seen in the diagram on the right, or the boron anomaly. Global models also reflect interesting developments of glass property measurement accuracy, e.g., a decreasing accuracy of experimental data in modern scientific literature for some glass properties, shown in the diagram. They can be used for accreditation of new data, experimental procedures, and measurement institutions (glass laboratories). In the following sections (except melting enthalpy) empirical modeling techniques are presented, which seem to be a successful way for handling huge amounts of experimental data. The resulting models are applied in contemporary engineering and research for the calculation of glass properties.

Non-empirical (deductive) glass models exist.[20] They are often not created to obtain reliable glass property predictions in the first place (except melting enthalpy), but to establish relations among several properties (e.g. atomic radius, atomic mass, chemical bond strength and angles, chemical valency, heat capacity) to gain scientific insight. In future, the investigation of property relations in deductive models may ultimately lead to reliable predictions for all desired properties, provided the property relations are well understood and all required experimental data are available.

Methods

Glass properties and glass behavior during production can be calculated through statistical analysis of glass databases such as GE-SYSTEM[21] SciGlass[22] and Interglad,[23] sometimes combined with the finite element method. For estimating the melting enthalpy thermodynamic databases are used.

Linear regression

If the desired glass property is not related to crystallization (e.g., liquidus temperature) or phase separation, linear regression can be applied using common polynomial functions up to the third degree. Below is an example equation of the second degree. The C-values are the glass component concentrations like Na2O or CaO in percent or other fractions, the b-values are coefficients, and n is the total number of glass components. The glass main component silica (SiO2) is excluded in the equation below because of over-parametrization due to the constraint that all components sum up to 100%. Many terms in the equation below can be neglected based on correlation and significance analysis. Systematic errors such as seen in the picture are quantified by dummy variables. Further details and examples are available in an online tutorial by Fluegel.[24]

Non-linear regression

The liquidus temperature has been modeled by non-linear regression using neural networks[26] and disconnected peak functions.[25] The disconnected peak functions approach is based on the observation that within one primary crystalline phase field linear regression can be applied[27] and at eutectic points sudden changes occur.

Glass melting enthalpy

The glass melting enthalpy reflects the amount of energy needed to convert the mix of raw materials (batch) to a melt glass. It depends on the batch and glass compositions, on the efficiency of the furnace and heat regeneration systems, the average residence time of the glass in the furnace, and many other factors. A pioneering article about the subject was written by Carl Kr?ger in 1953.[28] More recently, R. Conradt at RWTH Aachen, Germany, is a leading expert in this field.[29]

Finite element method

For modeling of the glass flow in a glass melting furnace the finite element method is applied commercially,[30][31] based on data or models for viscosity, density, thermal conductivity, heat capacity, absorption spectra, and other relevant properties of the glass melt. The finite element method may also be applied to glass forming processes.

Optimization

It is often required to optimize several glass properties simultaneously, including production costs. GE-SYSTEM[32] [33] This can be performed, e.g., by simplex search, or in a spreadsheet as follows:

1 Listing of the desired properties;
2 Entering of models for the reliable calculation of properties based on the glass composition, including a formula for estimating the production costs;
3 Calculation of the squares of the differences (errors) between desired and calculated properties;
4 Reduction of the sum of square errors using the Solver option[34] in Microsoft Excel with the glass components as variables. Other software (e.g. Microcal Origin) can also be used to perform these optimizations.

It is possible to weight the desired properties differently. Basic information about the principle can be found in an article by Huff et al.[35] The combination of several glass models together with further relevant technological and financial functions can be used in six sigma optimization.